First, save the data in an excel file and import into Matlab using File>import data as shown below
Data is saved into a local variable most likely called "untitled". Use this variable and extract your parameters. Then call cftool to start curve fitting toolbox
Curve fitting toolbox lets you decide what kind of function you'd like to use, and outputs statistical data to let you know how good the fit occurred.
The link below shows how to do this by using an older version of Matlab.
http://www.swarthmore.edu/NatSci/echeeve1/Ref/MatlabCurveFit/MatlabCftool.html
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